Electrical Engineering
      and Computer Sciences

Electrical Engineering and Computer Sciences

COLLEGE OF ENGINEERING

UC Berkeley

Kinetics of Photoresist Etching in an Electron Cyclotron Resonance Plasma

D.A. Carl, D.W. Hess and Michael A. Lieberman

EECS Department
University of California, Berkeley
Technical Report No. UCB/ERL M90/25
1990

An electron cyclotron resonance (ECR) plasma processing system was used to etch hardbaked KTI820 photoresist from single crystal silicon wafers, silicon dioxide films and patterned multilayer structures. Etch rates of 1500 nm/minute were observed at a substrate temperature below 373 K in a Pforward = 750 W, 0.13 Pa ECR oxygen plasma with no applied substrate bias. The etch rate increased linearly with increasing power from Pforward = 300 to 750 W. Etch rate was a complicated function of pressure and residence time, but a modified adsorption--reaction--ion-stimulated desorption rate expression could be used to fit the data. Etch rates decreased for increasing oxygen residence time at low operating pressures due to a combination of polymeric film formation of reaction products and reactant (atomic oxygen) depletion. Maximum etch rates were observed at approximately 0.13 Pa for all residence times. Multilayer photoresist structures were etched at various pressures as well as at a 45 degree angle to the incident plasma stream. Etch profiles for the variable angle runs indicated that the etch rate was strongly dependent on ion flux. Etch anisotropy increased with decreasing pressure, consistent with increased ion bombardment energy. The degree of anisotropy was, however, limited due to a non-normal component of ion energy, which has been interpreted previously as an ion temperature.


BibTeX citation:

@techreport{Carl:M90/25,
    Author = {Carl, D.A. and Hess, D.W. and Lieberman, Michael A.},
    Title = {Kinetics of Photoresist Etching in an Electron Cyclotron Resonance Plasma},
    Institution = {EECS Department, University of California, Berkeley},
    Year = {1990},
    URL = {http://www.eecs.berkeley.edu/Pubs/TechRpts/1990/1447.html},
    Number = {UCB/ERL M90/25},
    Abstract = {An electron cyclotron resonance (ECR) plasma processing system was used to etch hardbaked KTI820 photoresist from single crystal silicon wafers, silicon dioxide films and patterned multilayer structures. Etch rates of 1500 nm/minute were observed at a substrate temperature below 373 K in a Pforward = 750 W, 0.13 Pa ECR oxygen plasma with no applied substrate bias. The etch rate increased linearly with increasing power from Pforward = 300 to 750 W.  Etch rate was a complicated function of pressure and residence time, but a modified adsorption--reaction--ion-stimulated desorption rate expression could be used to fit the data. Etch rates decreased for increasing oxygen residence time at low operating pressures due to a combination of polymeric film formation of reaction products and reactant (atomic oxygen) depletion. Maximum etch rates were observed at approximately 0.13 Pa for all residence times. Multilayer photoresist structures were etched at various pressures as well as at a 45 degree angle to the incident plasma stream. Etch profiles for the variable angle runs indicated that the etch rate was strongly dependent on ion flux. Etch anisotropy increased with decreasing pressure, consistent with increased ion bombardment energy.  The degree of anisotropy was, however, limited due to a non-normal component of ion energy, which has been interpreted previously as an ion temperature.}
}

EndNote citation:

%0 Report
%A Carl, D.A.
%A Hess, D.W.
%A Lieberman, Michael A.
%T Kinetics of Photoresist Etching in an Electron Cyclotron Resonance Plasma
%I EECS Department, University of California, Berkeley
%D 1990
%@ UCB/ERL M90/25
%U http://www.eecs.berkeley.edu/Pubs/TechRpts/1990/1447.html
%F Carl:M90/25